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Chemical Recycling of Mixed Plastic Waste

First-class Technology for Chemical Plastic Recycling

Plastic waste, especially packaging waste, is generally a mixture of materials with a high degree of contamination. Recycling this raw material is usually difficult, as sorting and cleaning of waste is in many cases neither economically viable nor technically feasible. Chemical recycling is a promising process to recycle these material streams into chemicals, waxes or liquid energy carriers.  

Coperion provides first-class technologies for the chemical recycling of post-consumer waste. Coperion K-Tron feeders ensure high-accuracy feeding of raw materials into the extruder. Coperion’s ZSK twin screw extruders possess numerous advantages that are especially beneficial for an energy efficient chemical recycling process.

Coperion Process for Chemical Recycling of Plastics

Chemical Recycling – The Process

Chemical recycling is a promising process for recycling mixed plastic waste, both technically and economically.

After post-consumer waste, either shredded or compacted, is reliably added to the extruder’s process section by a high-accuracy Coperion K-Tron feeder, a great deal of mechanical energy is introduced into the material in shortest time thanks to the continuous surface renewal as well as intensive dispersion and shearing along the twin screws.

Within about 30 seconds, a homogeneous, highly devolatilized melt with a temperature of up to 350°C is produced, into which the energy has been introduced very efficiently.

Further materials, such as catalysts, can be added and mixed in as needed. In some cases, residual water or chlorides from PVC are introduced into the extruder in minute quantities along with the plastic waste. Both are reliably extracted via vacuum devolatilization on the extruder's process section.

Within the reactor, the melt, which was previously heated to up to 350°C in the twin screw extruder, is further heated. At up to 500°C pyrolysis of the polymers takes place, the splitting of polymer chains into shorter units in an oxygen-free environment. The pyrolysis of polymers utilizes the random scission mechanism, where free radicals are generated. At the same time, chain reactions are initiated which lead to cracking polymers into a broad mixture of hydrocarbons in liquid and gaseous phase. The most important factors for driving this process are residence time, temperature, and the type of pyrolysis agent.

Most of the inorganic components of the post-consumer waste remain in the reactor's sump and are removed. The polymers’ organic hydrocarbons evaporate. They are transformed into monomers, petrochemical raw materials, or synthesis gases and then processed further in a destillator into marketable products such as oil, heavy fuel, or waxes.

COMPREHENSIVE PRODUCT RANGE

Coperion ZSK twin screw extruder

ZSK Twin Screw Extruders

Coperion’s twin screw extruder technology is particularly well suited for an efficient energy addition and therefore for chemical recycling of plastics. Twin screw extruders possess numerous advantages that are especially beneficial in chemical recycling. The technology covers a broad range of throughputs. On larger ZSK extrusion machines, throughputs of up to 20 t/h can be realized. Polymers of various viscosities are reliably plastified thanks to the highly effective mode of operation of the twin screws. Plastic energy dissipation takes place in no time. When needed, corrosion and wear protection of all product-contact parts within the process section can assure long extruder lifetime even when processing very aggressive materials.

ZSK Mc¹⁸ Twin Screw Extruders
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Feeding Equipment

Coperion K-Tron feeders secure high-accuracy feeding of raw ingredients into the extrusion process. The wide range of products available includes twin screw feeders, single screw feeders, bulk solids pumps, vibratory feeders as well as other types in a variety of sizes and configurations. Coperion K-Tron feeders ensure a continuous, uniform infeed with a very tight short-term accuracy and repeatability.

Volumetric and Gravimetric Feeders

Service

From single spare parts to total services, Coperion and Coperion K-Tron provide comprehensive maintenance and modernization of plastic recycling systems.

Service

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